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    Why does water expand when it freezes as opposed to most other liquids that shrink in volume?

    Question #36823. Asked by Bryce-.

    sequoianoir

    The simple answer is that it is at its most dense state at 4 degrees centigrade. It it less dense both above and below this point.

    Jul 29 03, 5:41 PM
    gmackematix

    The more complex answer is that the crystal packing arrangement of water molecules in ice takes up more space than the hydrogen bonded H2O molecules do when flowing over one another in a liquid state.
    I think the element gallium is also denser when molten.

    Jul 29 03, 6:55 PM

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