gtho4 might have the answer but have a look at my settings, just in case something seems amiss with yours. These work for me:
Open up the account 'Properties' by right-clicking on the account name in the left-hand column. Choose 'Properties' from the menu. If you're creating new accounts, this information might also help with that too.
Under the 'General' tab:
In the top field (box) type a name for the e-mail account (it can be anything). Then..
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Name: type the email address before the '@' leaving out everything after.
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Organization: Leave blank.
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E-mail address: Type the full e-mail address.
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Reply address: Leave blank.
Screenshot of the aboveSwitch to the 'Servers' tab:
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My incoming mail server is a: 'POP3'
server.
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Incoming mail (POP3): pop.
yourISPname.com (or dot whatever)
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Outgoing mail (SMTP): smtp.
yourISPname.com (or dot whatever)
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Email username: type the email address before the '@' leaving out everything after.
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Password: Password
Screenshot of the aboveSwitch to the 'Advanced' tab:
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Outgoing mail: (SMTP): 25
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Incoming mail: (POP3): 110.
Screenshot of the above